According to Martin (2001) ‘glass
can generally be divided into two groups: oxide glass and non-oxide glass. The
ingredients of oxide glasses include oxides (chemical compounds that
include oxygen). Non-oxide glasses are made from compounds that contain no
oxides, and which often instead contain sulfides or metals. Oxide glasses are
much more widely used commercially’. The common types of glass and their
chemical composition can be found at: http://www.texasglass.com/glass_facts/composition_of_Glass.htm.
The predominant ingredient used
to manufacture glass is sand. Sand occurs naturally on earth by the disintegration
of rock and mineral particles. The main component of each grain of sand is
typically silicon dioxide and the presence of silicon (Si) on Earth occurred by
falling meteorites known as aerolites. The chemical compound silicon dioxide,
commonly known as silica (SiO2)
is the oxide of silicon.
The British Glass Manufacturer’s
Confederation (2011) describes on their website how glass is manufactured:
Glass is made
by melting together several minerals at very high temperatures. Silica in the
form of sand is the main ingredient and this is combined with soda ash and
limestone and melted in a furnace at temperatures of 1700°C. Other materials
can be added to produce different colours or properties. Glass can also be
coated, heat-treated, engraved or decorated. Whilst still molten, glass can be
manipulated to form packaging, car windscreens, glazing or numerous other
products. Depending on the end use, the composition of the glass and the rate
at which it is allowed to cool will vary, as these two factors are crucial in
obtaining the properties the glassmaker is seeking to achieve.
Key dates in the history of glass production:
Earliest origins Historians
have discovered that a form of natural glass - obsidian - formed for instance,within the mouth of a volcano as a result of the intense heat of an eruption
melting sand - was first used by man as tips for spears.
4000 BC (Egypt) Evidence of
man-made glass in the form of glazes used for coating stone beads.
1500 BC The first hollow
glass container was made by covering a sand core with a layer of molten glass.
43 AD – 410 AD The
secret of glass making came to Britain with the Romans!
680 AD Evidence
of a glass industry around Jarrow and Wearmouth.
13th Century
AD Evidence
of there having been a glass industry in the Weald and the afforested area of
Surrey and Sussex around Chiddingford.
1845 AD The
modern glass industry really started to develop in Britain after the repeal of
the Excise Act in 1845 relieved the heavy taxation that had been enforced.
1851 AD Joseph
Paxton's Crystal Palace at the Great Exhibition of 1851 marked the beginning of
the discovery of glass as a building material. The revolutionary new building encouraged the use of glass in public, domestic and horticultural architecture.
1887 AD Glass
making developed from traditional mouth blowing to a semi-automatic process.
1907 AD First
fully automated machine was developed in America.
Recycling glass has a positive impact on the environment
as it takes less energy to melt recycled glass than it does to melt down raw
materials. Recycling also reduces the need for raw materials to be quarried therefore
saving precious resources.
References:
The British Glass Manufacturer’s Confederation. (2011) About glass. Available at: http://www.britglass.org.uk/ (Accessed
4 February 2012).
Emsley, J. (2003) Nature’s
building blocks an A-Z guide to the elements. Oxford: Oxford University
Press.
Martin, S. (2001) Glass
facts composition of glass. Available at: http://www.texasglass.com/glass_facts/composition_of_Glass.htm
(Accessed: 4 February 2012).
http://wiki.answers.com/Q/How_do_you_a_make_wood_fire_burn_hotter
ReplyDeleteWhat exactly is added to make the different colours?
ReplyDeleteGillian
Vicky
ReplyDeleteI was interested to see your timeline, especially...
"13th Century AD Evidence of there having been a glass industry in the Weald and the afforested area of Surrey and Sussex around Chiddingford."
Can you tell us anything about the raw materials and the process they will have used???
lso, how hot does the fire need to be? Any chance we could do it in the wood (charcoal fire with constant air supply) if we sourced the raw materials? I guess not?
vicky mitchell
ReplyDelete04/08/2012 11:22pm
Hi Gillian, thank you for your post. That’s such an interesting question, one which I hadn’t thought about adding to the blog. I will research and get back to you.
Reply
Vicky Mitchell
ReplyDelete04/10/2012 12:21am
Hi Gillian, I've looked into 'how glass is coloured' and added a little bit of what I've found out to the blog. Hope you enjoy reading.
Color [sic] is the most obvious property of a glass object. It can also be one of the most interesting and beautiful properties. Although color [sic] rarely defines the usefulness of a glass object it almost always defines its desirability. (The Geological Society of America, 2012)
The earliest people who worked with glass would have had no control over its colour, however, by accident and experimentation glass makers learned that by adding certain substances to the glass melt they could produce glass finished in different colours. Furthermore, they discovered other substances that, when added to the melt, would remove colour from the finished project. (The Geological Society of America, 2012).
The substances used to colour glass are metals (The Geological Society of America, 2012). The table below gives details of what colour can be achieved by adding which metal.
Metals Used to Impart Colour to Glass
Cadmium Sulfide Yellow
Gold Chloride Red
Cobalt Oxide Blue-Violet
Manganese Dioxide Purple
Nickel Oxide Violet
Sulfur Yellow – Amber
Chromic Oxide Emerald Green
Uranium Oxide Fluorescent Yellow, Green
Iron Oxide Greens and Browns
Selenium Oxide Reds
Carbon Oxides Amber Brown
Antimony Oxides White
Copper Compounds Blue, Green, Red
Tin Compounds White
Lead Compounds Yellow
Manganese Dioxide A "decoloring" agent
Sodium Nitrate A "decoloring" agent
Some interesting facts:
ReplyDeleteEmsley (2003, p. 116) describes a small deep blue glass object being found amongst the treasures in the tomb of Pharaoh Tutankhamen, who ruled from 1361 to 1352 BC . The deep colour was achieved by using a cobalt mineral, providing evidence that this process was known to the ancient world; moreover, Emsley (2003, p. 116) also suggests that “it was known in China long before this time, however, and was used for pottery glazes, but it was always a rare pigment because cobalt minerals themselves are rare” (Emsley, 2003, p. 116). Emsley (2003, p. 117) further comments that “Cobalt blue is an important part of an artists’ palette of colours and is used by craft workers in porcelain, pottery, stained glass, tiles and enamel jewellery. Cobalt was particularly popular with glass bottle makers in the nineteenth century”.
Gold has been known since prehistoric times and was one of the first metals to be worked. (Emsley, 2003, p. 166). Collodial gold is precipitated when pure tin is added to gold that is dissolved in aqua regia (a chemical refining process. Wikipedia, 2012). After an hour a brilliant purple participate forms; this is known as Purple of Cassius and is named after Andreas Cassius of Potsdam, Germany, who first published the method of making it in 1685. The pigment was used to colour glass, to which it gave a ruby tint (Emsley, 2003, p. 167).
According to Emsley (2003, p. 477) during most of the nineteenth century, uranium was not regarded as particularly dangerous. It was used commercially and in 1855 a factory was set up in Austria to manufacture uranium pigments for colouring pottery and glass. Glass to which uranium oxide has been added has a fluorescent yellow-green colour.
In 1912, R. T. Gunther of Oxford University
excavated a first century AD Roman villa on
Cape Posilipo on the Bay of Naples, and came
across a mosaic in which there were curiously
coloured glass pieces. When these were
analysed it was discovered that their tint was
due to the presence of 1% uranium oxide,
and that this mineral must have been deliberately
added to colour the glass. (Emsley, 2003, p. 481).
If you would like to know more about the metals used to produce many more different colours or the chemistry involved have a look at this website http://1st-glass.1st-things.com/articles/glasscolouring.html David M. Issitt is a leading expert on English coloured glass, and the website does make for a fascinating read.
References:
‘Aqua Regia’ (2012) Wikipedia. Available at: http://en.wikipedia.org/wiki/Aqua_regia (Accessed: 9 April 2012).
Emsley, J. (2003) Nature’s Building Blocks An A-Z Guide to the Elements. Oxford: Oxford University Press.
The Geological Society of America (2012) Elements of Color in Stained Colored Glass. Available at: http://geology.com/articles/color-in-glass.shtml (Accessed: 3 April 2012)
13th Century AD Glass Industry - Vicky
ReplyDeleteHi guys, I’ve spent hours trying to research “13th century AD evidence of there having been a glass industry in the Weald and the afforested area of Surrey and Sussex around Chiddingfold;” I’ve even emailed The British Glass Manufacturer’s Confederation who was the source I quoted and unfortunately as of yet they haven’t replied. However, I have found several references to a glass industry in that area during that period but regrettably one of the sources I’m using is Wikipedia.
A property website (Surreyproperty.com) describes the glass industry in Chiddingfold in their history of the area:
Between the 13th and 16th centuries Chiddingfold developed as a nationally important centre for the manufacture of glass. Locally produced charcoal was used to fire the furnaces and all the ingredients of glass were readily available in the area. Both glass vessels and window glass were produced. In 1352 a Chiddingfold glassworks supplied large quantities of glass for St Stephen's Chapel at Westminster and, in 1356, the same works supplied the glass for the windows of St George's Chapel at Windsor.
Glassmaking and also the production of iron in this part of Surrey seriously depleted the oak forests, which was of great concern to the government. Timber was increasingly in demand for the ships of England's growing navy and the government was anxious to conserve stocks. Statutes were passed to control the amount of timber taken for the production of charcoal. However, it was the development of coal-fired furnaces which finally took these industries away to other parts of England in the 17th century.
http://www.surreyproperty.com/chiddingfold-history.html
13th Century Glass industry (PART 2) - Vicky.
ReplyDeleteWikipedia’s entries state:
Glass making
The glass making industry started on the Sussex/ Surrey border in the early 13th century and flourished till the 17th century.[133] The industry, in Sussex, during the 16th century spread to Wisborough Green then to Alfold, Ewhurst, Billinghurst and Lurgashall.[133] Many of the artisans in the industry were immigrants from France and Germany.[133] The manufacturing process used timber for fuel, sand and potash(which served as flux).[134]
Glass production in the English midlands using coal for the smelting process, plus opposition to the use of timber in Sussex, led to the collapse of the Sussex glass making industry in 1612.[133]
http://en.wikipedia.org/wiki/History_of_Sussex#Glass_making
Wikipedia’s reference source [133]:
Brandon, Peter, ed. (1978). The South Saxons. Chichester: Phillimore. ISBN 0-85033-240-0.
Brandon, Peter (2006). Sussex. London: Robert Hale. ISBN 0-7090-6998-7.
Glass Production
The glassmaking operation required three furnaces with different sizes. The first furnace was for melting the glass, the smaller one for annealing or cooling the finished glass. And an even smaller fritting furnace for preheating the ingredients needed for making the glass. A fourth furnace was erected to fire up the clay pots used in the glassmaking process. The construction of the furnaces was made up of huge boulders rolled out of the river and glued together with mud. A rectangular wood-frame building was constructed to protect the furnaces and the workers from the weather. Overall the glass house was about thirty seven feet wide by fifty feet long, and probably had a high thatched roof and partially open sides with the office situated next to the furnaces.
http://en.wikipedia.org/wiki/History_of_glass#Evidence_of_glass_making
If you would like to see some glass from that era head to The Parish Church dedicated to St. Mary in Chiddingfold as “427 fragments of original Chiddingfold glass (13th to 16th century) of which 224 are coloured, used as found, have been leaded to form the lancet window you see to the right of the Font. There is a plaque describing it on the west wall below the window. The Jubilee Window of Queen Victoria to the left is of Whitefriars glass.”
Extracts from 'A Guide for our Visitors' by H.R.H. White (1983)
http://www.johnowensmith.co.uk/churches/chiddini.htm